Ring Opening of Bicyclo[n.1.0]alkanones to 2-Cycloalkanone-1,3-diyls. Why Does Oxyallyl Diradical Formation Require Less Energy from Bicyclo[3.1.0]hexan-6-ones than from Bicyclo[1.1.0]butan-2-ones?
Author:
Affiliation:
1. Contribution from the Departments of Chemistry, University of Washington, Box 351700, Seattle, Washington 98195-1700, and University of Calgary, Calgary, Alberta T2N 1N4, Canada
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja954296y
Reference26 articles.
1. A new synthesis of in situ cyclopropanones and the observation of a thermal cyclopropanone–dienol rearrangement
2. Preparation and Structure Investigations of Simple Bicyclo[1.1.0]butanones
3. Attempted Generation of an Observable Ethano-Bridged (Cyclopentyl) Oxyallyl. The Pericyclic Nature of an Oxyallyl-Oxyallyl Dimerization Reaction
4. Ab initio computational study of methano- and ethano-bridged derivatives of oxyallyl
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1. The Pivotal Role of Oxyallyl Diradicals in Photo-Favorskii Rearrangements: Transient Spectroscopic and Computational Studies;Journal of the American Chemical Society;2013-09-30
2. Stretch Effects Induced by Molecular Strain on Weakening σ-Bonds: Molecular Design of Long-Lived Diradicals (Biradicals);The Journal of Organic Chemistry;2012-08-24
3. A Photo-Favorskii Ring Contraction Reaction: The Effect of Ring Size;The Journal of Organic Chemistry;2012-06-19
4. ChemInform Abstract: Ring Opening of Bicyclo(n.1.0)alkanones to 2-Cycloalkanone-1,3-diyls. Why Does Oxyallyl Diradical Formation Require Less Energy from Bicyclo( 3.1.0)hexan-6-ones than from Bicyclo(1.1.0)butan-2-ones?;ChemInform;2010-08-05
5. Electronic Structure and Spectroscopy of Oxyallyl: A Theoretical Study;The Journal of Physical Chemistry A;2010-06-15
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