A B3LYP Study of the Effects of Phenyl Substituents on 1,5-Hydrogen Shifts in 3-(Z)-1,3-Pentadiene Provides Evidence Against a Chameleonic Transition Structure-Reference-Cited by-同舟云学术

A B3LYP Study of the Effects of Phenyl Substituents on 1,5-Hydrogen Shifts in 3-(Z)-1,3-Pentadiene Provides Evidence Against a Chameleonic Transition Structure

Published:2004-07-24 Issue:32 Volume:126 Page:10028-10034
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Hayase Shuichi¹,Hrovat David A.¹,Borden Weston Thatcher¹

Affiliation:

1. Contribution from the Department of Chemistry, Box 351700, University of Washington, Seattle, Washington 98195-1700

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja048708r

Reference37 articles.

1. Variable transition state structure in 3,3-sigmatropic shifts from .alpha.-secondary deuterium isotope effects

2. A study of the mechanism of the Cope rearrangement

3. A frustrated Cope rearrangement: thermal interconversion of 2,6-diphenylhepta-1,6-diene and 1,5-diphenylbicyclo[3.2.0]heptane

4. Perturbation of the Degenerate, Concerted Cope Rearrangement by Two Phenyl Groups in Active Positions of (E)-1,4-Diphenylhexa-1,5-diene. Acceleration by High Pressure as Criterion of Cyclic Transition States

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