Anti-Markovnikov Addition of Both Primary and Secondary Amines to Terminal Alkynes Catalyzed by the TpRh(C2H4)2/PPh3 System

Author:

Fukumoto Yoshiya1,Asai Harumi1,Shimizu Masaki1,Chatani Naoto1

Affiliation:

1. Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference22 articles.

1. For reviews on the chemistry of imines and enamines, see:  (a) Sammakia T.; Abramite, J. A.; Sammons, M. F. Product Subclass of 6:  Enamines. InScience of Synthesis; Molander, M., Ed.; Georg Thieme Verlag:  Stuttgart, 2006; pp 405−411. (b) Adams, J. P.J. Chem. Soc., Perkin Trans. 12000, 125. (c) Kuckländer, U. InThe Chemistry of Enamines; Rappoport, Z., Ed.; Wiley-VCH:  New York, 1994; pp 523−636.

2. Intra- and Intermolecular Hydroamination of Alkynes Catalyzed by ortho-Metalated Iridium Complexes

3. Intermolecular Hydroamination of Terminal Alkynes Catalyzed by Organoactinide Complexes. Scope and Mechanistic Studies

4. Organoactinide-Catalyzed Intermolecular Hydroamination of Terminal Alkynes

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