Mechanism of the Formation of Carbyne Complexes of Rhenium upon Protonation of Vinylidene Precursors
Author:
Affiliation:
1. Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, Av. Rovisco Pais, 1096 Lisboa codex, Portugal
2. Nitrogen Fixation Laboratory, John-Innes Centre, Norwich Research Park, Colney Lane, Norwich NR4 7UH, U.K.
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om970398g
Reference23 articles.
1. Protonation of coordinated dinitrogen
2. Protonation of the nitrite ligand versus protonation of rhenium at cis- or trans-[ReCl(NCC6H4R-4)(Ph2PCH2CH2PPh2)2] (R Cl, F, Me or MeO). A mechanistic study
3. Carbon is not the initial site of attack in the protonation of an allene ligand to give an η2-vinyl species: kinetic studies on trans-[CPh)- (Ph2PCH2CH2PPh2)2]
4. Aminocarbyne coupling reactions at M(Ph2PCH2CH2PPh2)2(M = Mo or W) sites. Detailed mechanistic studies on the protonation of co-ordinated isocyanides and coupling of ligands in trans-[M(CNR)2(Ph2PCH2CH2PPh2)2](R = But or Me)
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