Synergetic Dimetallic Effects in Gaudemar/Normant Coupling between Allylzinc and Vinyl Grignard Reagents

Author:

Hirai Atsushi1,Nakamura Masaharu1,Nakamura Eiichi1

Affiliation:

1. Department of Chemistry, The University of Tokyo Bunkyo-ku, Tokyo 113-0033, Japan

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference17 articles.

1. In consonance with the intuition, model B3LYP/6-31+G* calculations indicated that 1,1-dianion formation is 108 kcal/mol endothermic and the adduct would tend to decompose back to the two anions.

2. Mixed gem-dimetallic organic compounds. A new class of multi-coupling reagents part 2

3. Copper Pnictogenides as Selective Reagents: A New Access to Functionalized Phosphanes and Arsanes

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