Synergetic Dimetallic Effects in Gaudemar/Normant Coupling between Allylzinc and Vinyl Grignard Reagents
Author:
Affiliation:
1. Department of Chemistry, The University of Tokyo Bunkyo-ku, Tokyo 113-0033, Japan
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja9914590
Reference17 articles.
1. In consonance with the intuition, model B3LYP/6-31+G* calculations indicated that 1,1-dianion formation is 108 kcal/mol endothermic and the adduct would tend to decompose back to the two anions.
2. Mixed gem-dimetallic organic compounds. A new class of multi-coupling reagents part 2
3. Copper Pnictogenides as Selective Reagents: A New Access to Functionalized Phosphanes and Arsanes
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