Controversial Exothermicity of the Oxidative Addition of Methane to (Cyclopentadienyl)rhodium Carbonyl
Author:
Affiliation:
1. Department of Chemistry, Texas A&M University, College Station, Texas 77843-3255
Publisher
American Chemical Society (ACS)
Subject
Physical and Theoretical Chemistry,General Engineering
Link
https://pubs.acs.org/doi/pdf/10.1021/jp9609693
Reference12 articles.
1. Gas-Phase Rates of Alkane C-H Oxidative Addition to a Transient CpRh(CO) Complex
2. IR Flash Kinetic Spectroscopy of C-H Bond Activation of Cyclohexane-d0 and -d12 by Cp*Rh(CO)2 in Liquid Rare Gases: Kinetics, Thermodynamics, and Unusual Isotope Effect
3. Theoretical study on the electronic and molecular structures of (C5H5)M(L) (M = rhodium, iridium; L = carbonyl, phosphine) and M(CO)4 (M = ruthenium, osmium) and their ability to activate the carbon-hydrogen bond in methane
4. Theoretical studies of inorganic and organometallic reaction mechanisms. 6. Methane activation on transient cyclopentadienylcarbonylrhodium
5. Ab Initio Molecular Orbital Study of the Mechanism of H-H, C-H, N-H, O-H and Si-H Bond Activation on Transient Cyclopentadienylcarbonylrhodium
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1. Probing the Carbon–Hydrogen Activation of Alkanes Following Photolysis of Tp′Rh(CNR)(carbodiimide): A Computational and Time-Resolved Infrared Spectroscopic Study;Journal of the American Chemical Society;2018-01-25
2. A model study on the photodecarbonyl reaction of (η5-C5H5)M(CO)2 (M = Co, Rh, Ir);RSC Advances;2018
3. Theoretical and Computational Study of a Complex System Consisting of Transition Metal Element(s): How to Understand and Predict Its Geometry, Bonding Nature, Molecular Property, and Reaction Behavior;Bulletin of the Chemical Society of Japan;2015-07-15
4. Synthesis and characterization of cationic rhodium(I) dicarbonyl complexes;Inorganica Chimica Acta;2011-02
5. Combined experimental and theoretical investigation into C–H activation of cyclic alkanes by Cp′Rh(CO)2 (Cp′ = η5-C5H5 or η5-C5Me5);Dalton Transactions;2011
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