Reactivity of Tuck-in and Tuck-over Uranium Metallocene Complexes
Author:
Affiliation:
1. Department of Chemistry, University of California, Irvine, California 92697-2025
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om1007538
Reference54 articles.
1. A Crystallizable f-Element Tuck-In Complex: The Tuck-in Tuck-over Uranium Metallocene [(C5Me5)U{μ-η5:η1:η1-C5Me3(CH2)2}(μ-H)2U(C5Me5)2]
2. .sigma.-Bond metathesis for carbon-hydrogen bonds of hydrocarbons and Sc-R (R = H, alkyl, aryl) bonds of permethylscandocene derivatives. Evidence for noninvolvement of the .pi. system in electrophilic activation of aromatic and vinylic C-H bonds
3. Reactivity of samarium complex [(C5Me5)2Sm(.mu.-H)]2 in ether and arene solvents. X-ray crystal structures of the internally metalated complex (C5Me5)2Sm(.mu.-H)(.mu.-CH2C5Me4)Sm(C5Me5), the benzyl complex (C5Me5)2Sm(CH2C6H5)(THF), and the siloxide complex [(C5Me5)2Sm(THF)]2(.mu.-OSiMe2OSiMe2O)
4. Carbon-hydrogen activation of arenes and substituted arenes by the yttrium hydride (Cp*2YH)2: competition between Cp* ligand metalation, arene metalation, and hydrogen/deuterium exchange. Molecular structures of Cp*2Y(.mu.-H)(.mu.-.eta.1,.eta.5-CH2C5Me4)YCp* and Cp*2Y(o-C6H4PPh2CH2)
5. Trialkylboron/Lanthanide Metallocene Hydride Chemistry: Polydentate Bridging of (HBEt3)- to Lanthanum
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