Theoretical Analysis of the Diradical Nature of Adenosylcobalamin Cofactor−Tyrosine Complex in B12-Dependent Mutases: Inspiring PCET-Driven Enzymatic Catalysis
Author:
Affiliation:
1. Department of Chemistry, University of Louisville, Louisville, Kentucky 40292, and Institute for Materials Chemistry and Engineering, Kyushu University, Nishi-ku, Fukuoka 819-0395, Japan
Publisher
American Chemical Society (ACS)
Subject
Materials Chemistry,Surfaces, Coatings and Films,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jp100573b
Reference109 articles.
1. aMarzilli, L. G.InBioinorganic Catalysis;Reedijk, J., Ed.Marcel Dekker:New York, 1993; pp227−259.
2. Vitamin B12 and B12‐Proteins
3. Radical Catalysis in Coenzyme B12-Dependent Isomerization (Eliminating) Reactions
4. Radical catalysis of B 12 enzymes: structure, mechanism, inactivation, and reactivation of diol and glycerol dehydratases
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