1. Institute of Mineralogy/Environmental Analytic, J.W. Goethe−University, Georg-Voigt-Strasse 16, D-60054 Frankfurt am Main, Germany, Institute of Spectrochemistry and Applied Spectroscopy, Bunsen-Kirchhoff-Strasse 11, D-44139 Dortmund, Germany, and Hessisches Landesamt für Umwelt und Geologie, Rheingaustrasse 186, D-65203 Wiesbaden, Germany