C−O Bond Homolysis in a Tungsten Alkoxide: The Mechanism of Alcohol Deoxygenation by WCl2(PMe3)4 and WH2Cl2(PMe3)4
Author:
Affiliation:
1. Contribution from the Department of Chemistry, Box 351700, University of Washington, Seattle, Washington 98195-1700
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja970929s
Reference41 articles.
1. Pyrolytic transformation of metal alkoxides to oxides: mechanistic studies. Pyrolysis of homoleptic titanium alkoxides
2. Molecular Routes for the Synthesis of Metal Carbides, Nitrides, and Oxides. 1. Studies of the Thermal Decomposition of M2(OR)6 and M2(CH2Ph)2(OR)4 Compounds Where M = Mo and W
3. Gated electron-transfer behavior in copper(II/I) systems. Comparison of the kinetics for homogeneous cross reactions, NMR self-exchange relaxation, and electrochemical data for a copper macrocyclic tetrathioether complex in aqueous solution
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