Atom-Economical Synthesis of the Versatile Ruthenium Precursor [TpRuCl(COD)] (Tp = Hydrotris(pyrazol-1-yl)borate) Discloses a Diamine Ligand Dealkylation Process
Author:
Affiliation:
1. Departamento de Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica-INBIO, Facultad de Ciencias, Universidad de Cádiz, 11510 Puerto Real, Cádiz, Spain
Funder
Junta de Andalucía
Ministerio de Economia y Competitividad
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om501307a
Reference25 articles.
1. Ruthenium Tris(pyrazolyl)borate Complexes. 1. Synthesis and Reactivity of Ru(HB(pz)3)(COD)X (X = Cl, Br) and Ru(HB(pz)3)(L2)Cl (L = Nitrogen and Phosphorus Donor Ligands)
2. Synthesis and reactivity of neutral vinylidene and σ-alkynyl complexes containing the hemilabile ligand Ph2PCH2CH2OMe
3. Reaction of Diaryl Disulfides with RuTp(COD)Cl in N,N‘-Dimethylformamide: Formation of 2-(Arylmercapto)aryl Mercaptan Complexes
4. Reactions of the Cationic Fragments [RuCp(PPh2NHR)2]+ and [RuTp(PPh2NHR)2]+ (R = Ph, n-Pr) with Alkynes: Formation of Four-Membered Azaphosphacarbenes
5. Synthesis and Reactivity of the Ru III Complexes [RuTp(PR 3 )Cl 2 ] — Precursors for RuTp Dihydrogen Complexes
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1. Syntheses, structures and immobilization of ruthenium complexes bearing N , O -Schiff-base or N , N′ -diamine ligands functionalized with alkoxysilyl groups;Journal of Organometallic Chemistry;2018-01
2. Direct Chlorination of Trispyrazolyl Borate Ligands in Tp-Ruthenium Complexes;Organometallics;2017-11-20
3. Activation of Propargyl Alcohols by TpRu Complexes Bearing a Bidentate NHC Ligand;Organometallics;2016-01-29
4. Golden Jubilee for Scorpionates;Advances in Organometallic Chemistry;2016
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