Complete Reversal in Regioselectivity in the Baeyer−Villiger Reaction of an α-CF3-Ketone and Theoretical Rationale for Axial Orientation of Sterically Demanding CF3 Group at the Transition State-Reference-Cited by-同舟云学术

Complete Reversal in Regioselectivity in the Baeyer−Villiger Reaction of an α-CF3-Ketone and Theoretical Rationale for Axial Orientation of Sterically Demanding CF3 Group at the Transition State

Published:2003-11-14 Issue:25 Volume:5 Page:4803-4806
ISSN:1523-7060
Container-title:Organic Letters
language:en
Short-container-title:Org. Lett.

Author:

Itoh Yoshimitsu¹,Yamanaka Masahiro¹,Mikami Koichi¹

Affiliation:

1. Department of Applied Chemistry, Tokyo Institute of Technology, Tokyo 152-8552, Japan

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ol0358298

Reference21 articles.

1. Ortsbestimmungen in der Terpenreihe

2. Darstellung und Veresterung tertiärer Hydroperoxyde

3. Structural Effects on the Polymerization of Lactams

4. Variation of carbon-14 isotope effect with substituent and the mechanism of the m-chloroperbenzoic acid oxidation of laeled para-substituted acetophenones

Cited by 31 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. A Unifying Bioinspired Synthesis of (−)-Asperaculin A and (−)-Penifulvin D;Organic Letters;2021-04-08

2. Enantioselective synthesis of trifluoromethyl substituted cyclohexanones via an organocatalytic cascade Michael/aldol reaction;Organic & Biomolecular Chemistry;2020

3. Synthesis of unstrained Criegee intermediates: inverse α-effect and other protective stereoelectronic forces can stop Baeyer–Villiger rearrangement of γ-hydroperoxy-γ-peroxylactones;Chemical Science;2020

4. Reinvestigation of Acetophenones Oxidation by Performic Acid in Formic Acid;The Journal of Physical Chemistry A;2019-02-21

5. Overriding Traditional Electronic Effects in Biocatalytic Baeyer–Villiger Reactions by Directed Evolution;Journal of the American Chemical Society;2018-07-25