Why Are (NN2)Ni Pincer Complexes Active for Alkyl−Alkyl Coupling: β-H Elimination Is Kinetically Accessible but Thermodynamically Uphill
Author:
Affiliation:
1. Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne (EPFL), SB-ISIC, Lausanne, CH 1015, Switzerland
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om1007506
Reference33 articles.
1. Metal‐Catalyzed Cross‐Coupling Reactions
2. Nickel-Catalyzed Cross-Couplings of Unactivated Alkyl Halides and Pseudohalides with Organometallic Compounds
3. Catalysts for Cross-Coupling Reactions with Non-activated Alkyl Halides
4. Secondary Alkyl Halides in Transition-Metal-Catalyzed Cross-Coupling Reactions
5. A New Nickel-Catalyzed Cross-Coupling Reaction between sp3 Carbon Centers
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