Scrambling of Oxygen-18 during the “Borderline” Solvolysis of 1-(3-Nitrophenyl)ethyl Tosylate
Author:
Affiliation:
1. Department of Biochemistry and Applied Chemistry, Kurume National College of Technology, Komorinomachi, Kurume 830-8555, Japan, and Department of Chemistry, University at Buffalo, SUNY, Buffalo, New York 14260
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ol0484409
Reference35 articles.
1. (a) Amyes, T. L.; Toteva, M. M.; Richard, J. P. InReactive IntermediateChemistry; Moss, R. A., Platz, M. S., Jones, M., Jr., Eds.; John Wiley & Sons: Hoboken, NJ, 2004, pp 41−68.
2. What Is the Stabilizing Interaction with Nucleophilic Solvents in the Transition State for Solvolysis of Tertiary Derivatives: Nucleophilic Solvent Participation or Nucleophilic Solvation?
3. Mechanism for Nucleophilic Substitution and Elimination Reactions at Tertiary Carbon in Largely Aqueous Solutions: Lifetime of a Simple Tertiary Carbocation
4. IUPAC recommendations for the representation of reaction mechanisms
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