Spectroscopic Detection and Theoretical Confirmation of the Role of Cr2(CO)5(C5R5)2 and ·Cr(CO)2(ketene)(C5R5) as Intermediates in Carbonylation of NNCHSiMe3 to OCCHSiMe3 by ·Cr(CO)3(C5R5) (R = H, CH3)-Reference-Cited by-同舟云学术

Spectroscopic Detection and Theoretical Confirmation of the Role of Cr2(CO)5(C5R5)2 and ·Cr(CO)2(ketene)(C5R5) as Intermediates in Carbonylation of NNCHSiMe3 to OCCHSiMe3 by ·Cr(CO)3(C5R5) (R = H, CH3)

Published:2007-10-26 Issue:46 Volume:129 Page:14388-14400
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Fortman George C.¹,Kégl Tamás¹,Li Qian-Shu¹,Zhang Xiuhui¹,Schaefer Henry F.¹,Xie Yaoming¹,King R. Bruce¹,Telser Joshua¹,Hoff Carl D.¹

Affiliation:

1. Contribution from the Department of Chemistry, University of Miami, Coral Gables, Florida, 33126, Department of Organic Chemistry, University of Pannonia, Veszprém, Hungary, The Institute for Chemical Physics, Beijing Institute of Technology, Beijing, 100081 People's Republic of China, Department of Chemistry and Center for Computational Chemistry, University of Georgia, Athens, Georgia 30606, and Department of Biological, Chemical and Physical Sciences, Roosevelt University, Chicago, Illinois 60605

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja075008o

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5. Reactions of 13 CO with Ethoxycarbonylcarbene‐Bridged Dicobalt Carbonyl Complexes: [μ 2 ‐{Ethoxycarbonyl(methylene)}‐μ 2 ‐(carbonyl)bis(tricarbonylcobalt)( Co – Co )] and [Di‐μ 2 ‐{ethoxycarbonyl(methylene)}bis(tricarbonylcobalt)( Co – Co )]

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