Iridacyclopentadiene Reactions with Terminal Alkynes: Tandem Cycloaromatization and Orthometalation
Author:
Affiliation:
1. Department of Chemistry and Biochemistry, 0358, 9500 Gilman Drive, University of California at San Diego, La Jolla, California 92093-0358
2. Department of Chemistry, University of Wyoming, Laramie, Wyoming 82071
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om0102450
Reference22 articles.
1. The First Metallacyclopentadiene(Alkyne) Complexes and Their Discrete Isomerization to η4-Bound Arenes: The Missing Link in the Prevalent Mechanism of Transition Metal Catalyzed Alkyne Cyclotrimerizations, as Exemplified by Cyclopentadienylcobalt
2. [2 + 2 + 1] Alkyne Cyclotrimerizations: A Metallacyclopentadiene Route to Fulvenes
3. Formation of a fulvene by trimerisation of an alkyne at a rhodium centre; crystal structure of cycloocta-1,5-diene(η5-1,3,6-tri-t-butylfulvene) rhodium hexafluorophosphate
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