Base-Promoted Hydroalkylation Reactions of the η5-C5Me5 Ligand Coordinated to Rhodium: Probing a Mechanism. New Compounds with the η5-C5Me4CF3 Ligand
Author:
Affiliation:
1. Department of Chemistry/216, University of NevadaReno, Reno, Nevada 89557
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om960213q
Reference44 articles.
1. Ring-Methyl Activation in Pentamethylcyclopentadienyl Complexes. 4. Syntheses, Structures, and Reactions of [(C5Me4CH2Cl)RuCl(CO)2] and Related Compounds: X-ray Structures of [(C5Me4CH2Cl)RuCl(CO)2] and [(C5Me4CH2OEt)Ru(PPh3)(CO)2](OTf)
2. Oxygen-induced methyl carbon-hydrogen activation in pentamethylcyclopentadienylruthenium complexes
3. Ring-methyl activation in pentamethylcyclopentadienyliridium complexes. Part 2. Synthesis of C5Me4(functionalized alkyl) complexes and crystal structures of [(C5Me4CH2CPh2OH)-IrMe(CO)Ph] and [(C5Me4CH2CO2H)IrMe(CO)Cl]
4. Deprotonation of 1,2,3,4,5-Pentamethylrhodocenium; a New Route to 1-Substituted-2,3,4,5-tetramethylcyclopentadienylrhodium Complexes
5. Ring-methyl activation in pentamethylcyclopentadienyliridium complexes; synthesis of [(C5Me4CH2E)IrLn] (E = SiMe3, PhCH2, CH2=CHCH2, PPh2, and Pt(PEt3)2Cl), and synthesis and X-ray structure of [(1,3-C5Me3(CH2SiMe3)2)Ir(CO)Me(Cl)]
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1. Intramolecular C–C Coupling Reactions of Alkynyl, Vinylidene, and Alkenylphosphane Ligands in Rhodium(III) Complexes;Organometallics;2016-08-30
2. Reactivity of κ(P)-Alkenylphosphane Rhodium(III) and Iridium(III) Complexes toward Nucleophilic Reagents;ChemistrySelect;2016-08-16
3. κ3(P,C,C)-Allylphosphane Iridium(III) and Rhodium(III) Complexes: Preparation and Reactivity toward Nucleophilic Reagents;Organometallics;2015-09-17
4. Oxidative additions on indenyl rhodium complexes bearing the hemilabile homoallyldiphenylphosphane (HADPP) ligand;Journal of Organometallic Chemistry;2014-05
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