Chemical and Thermal Behavior of the Molecular Models [Os3(CO)10(μ-H)(μ-OSiR2R‘)] (R = Et, Ph; R‘ = Et, Ph, OH, OSiPh2OH): Molecular Approach to the Clarification of the Surface Chemistry of the Silica-Anchored Cluster [Os3(CO)10(μ-H)(μ-OSi⋮)]
Author:
Affiliation:
1. Dipartimento di Chimica Inorganica, Metallorganica e Analitica and Centro CNR “CSSSCMTBSO”, Università di Milano, Via G. Venezian, 21, 20133 Milano, Italy
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om000858x
Reference64 articles.
1. Surface-supported metal cluster carbonyls. Chemisorption, decomposition and reactivity of Os3(CO)12, H2Os3(CO)10 and Os6(CO)18 supported on silica and alumina and the investigation of the fischer-tropsch catalysis with these systems
2. Surface supported metal cluster carbonyls. the surface organometallic chemistry of polymetallic and monometallic osmium carbonyl species formed by depositing various osmium clusters on silica and alumina
3. I.r. and E.X.A.F.S. characterisation of a supported osmium cluster carbonyl
4. Anchoring of cobalt, ruthenium, and osmium carbonyls to oxides by pendant thiol and phosphine ligands
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