Highly Enantioselective Chlorination of β-Keto Esters and Subsequent SN2 Displacement of Tertiary Chlorides: A Flexible Method for the Construction of Quaternary Stereogenic Centers
Author:
Affiliation:
1. Department of Environmental and Life Sciences, Toyohashi University of Technology, 1-1 Hibarigaoka, Tempaku-cho, Toyohashi 441-8580, Japan
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja304806j
Reference46 articles.
1. Stereospecific Construction of Chiral Quaternary Carbon Compounds from Chiral Secondary Alcohol Derivatives
2. 1,4,7-Trimethyloxatriquinane: SN2 Reaction at Tertiary Carbon
3. SN2 Displacement at Tertiary Carbon
4. Nucleophilic displacement at tertiary carbon
5. Halide exchange at a saturated carbon atom in dimethylformamide solvent. Comparison of experimental rates and Arrhenius parameters with values calculated by Ingold
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