A Short Enantioselective Total Synthesis of the Third-Generation Oral Contraceptive Desogestrel
Author:
Affiliation:
1. Contribution from the Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts, 02138
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja983179a
Reference19 articles.
1. A partial synthesis of 13-ethyl-11-methylene-18,19-dinor-17α-pregn-4-en-20-yn-17-ol (desogestrel) based upon intramolecular oxidation of an 11β-hydroxy-19-norsteroid to the 18 → 11β-lactone
2. Microbiological conversion of 19-nortestosterone: (II) 10- and 11-hydroxylation
3. Total synthesis of (+)-13-ethyl-3-methoxygona-1,3,5,9(11)-tetraen-17-one via the tandem Claisen-ene strategy
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