Protonation of CpCo(C4Me4): Ring-Opening with Formation of New σ,η4-Butadienyl and η5-Pentadienyl Cobalt Complexes
Author:
Affiliation:
1. Institut für Anorganische Chemie, Technische Hochschule Aachen, D-52056 Aachen, Germany, and Institut für Angewandte Synthesechemie, Technische Universität Wien, Getreidemarkt 9, A-1060 Wien, Austria
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om030146h
Reference17 articles.
1. Cyclobutadienemetal complexes
2. Cyclobutadiene-Metal Complexes. IV.1 (π-Cyclopentadienyl) (π-tetraphenylcyclobutadiene) palladium Halides and Related Complexes
3. Reaction of cationic cyclobutadineruthenium complexes with hydride anion donors; evidence for the formation of η4(5e) butadienyl species and fragmentation of the cyclobutadiene ring: crystal structure of [RuC(Ph)–η3-{C(Ph)·CH(Ph)·CH(Ph)}-(η-C5H5)] and [Ru2(µ-CO){µ-(Z)-C(Ph)CH(Ph)}(CO)2(η4-C4Ph4)(η-C5H5)]
4. Reactions of coordinated ligands. Part 47. Synthesis, structure, and reactivity of [.eta.4(5e)-butadienyl]ruthenium complexes: crystal structures of CpRu:C(Ph)-.eta.3-[C(Ph)C(Ph)CH(Ph)], CpRuC(Ph):C(Ph)-.eta.2-[C(Ph):CH(Ph)]P(OMe)3, and CpRu2[.mu.-(Z)-C(Ph):CH(Ph)](CO)2(.eta.4-C4Ph4)
5. Reactions of RuCp and RuCp* Allyl Carbene Complexes: Products Derived from Activation of Phenyl, Cyclohexyl, and Methyl C−H Bonds in PPh3, PCy3, and Cp* Ligands
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