Transition State Differences in Hydrolysis Reactions of Alkyl versus Aryl Phosphate Monoester Monoanions
Author:
Affiliation:
1. Contribution from the Utah State University, Department of Chemistry and Biochemistry, Logan, Utah 84322-0300
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja036571j
Reference33 articles.
1. The Reactivity of Phosphate Esters. Monoester Hydrolysis
2. Thatcher, G. R. J.; Kluger, R.Adv. Phys. Org. Chem.1989,25, 99; Hengge, A. C. InComprehensive Biological Catalysis: A MechanisticReference; Sinnott, M., Ed.; Academic Press: San Diego, CA, 1998; Vol. 1, p 517.
3. Transition-State Structures for Phosphoryl-Transfer Reactions of p-Nitrophenyl Phosphate
4. Evidence that metaphosphate monoanion is not an intermediate in solvolysis reactions in aqueous solution
5. The Substrate-Assisted General Base Catalysis Model for Phosphate Monoester Hydrolysis: Evaluation Using Reactivity Comparisons
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