C−S Bond Cleavage Routes to the Titanium−Sulfide Complexes (CpTi)6(μ3-S)4(μ3-O)4 and (CpTi)4(μ3-S)3(μ2-S)(μ2-SEt)2 (Cp = η-C5H5)
Author:
Affiliation:
1. Department of Chemistry and Biochemistry, University of Windsor, Windsor, ON, Canada N9B 3P4
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic961520r
Reference19 articles.
1. Excited-state chemistry of tetrakis(.mu.-pyrophosphito)diplatinum(II). Photoinduced addition of aryl bromides and iodides to the binuclear complex and the photoinduced catalytic conversion of isopropyl alcohol into acetone and hydrogen
2. Organometallic oxides and sulfides: preparation of [(η-C5H5)Ti]5(μ3-S)6, [(η-C5H5)Ti]5(μ3-S)5(μ3-S2)(μ4-O), and(η-C5H5)2Ti(SH)(μ-O)Ti(η-C5H5)(μ-S)2- Ti(η-C5H5)2 by reductive aggregation of (η-C5H5)2Ti(SH)2 with zinc powder or by oxidation of (η-C5H5)2Ti(CO)2 with H2S in the presence of water
3. Synthetic, structural, and theoretical studies on the electron-deficient cubanes (RC5H4)4Ti4S4, (RC5H4)4V4S4, and [(RC5H4)4V4S4]+.
4. Formation of an Anionic Titanium(IV) Sulfido Dimer, {Na2[CpTi(μ-S)(S)]2·4THF}2, by Elimination of CpH and H2 from Cp2Ti(SH)2 upon Deprotonation with NaH
5. Zur Reaktion von [Cp2TiCl2] und [CpTiCl3] mit E(SiMe3)2 (E = S, Se) Die Kristallstrukturen von [Cp3Ti2S2Cl], [Cp4Ti2S2Cl2], [Cp3Ti2Se2Cl] und [Cp4Ti4Se7O] / Reaction of [Cp2TiCl2] and [CpTiCl3 ] with E(SiMe 3)2 (E = S. Se) The Crystal Structures of [Cp3Ti2S2Cl], [Cp3Ti2S2Cl2], [Cp3Ti2Se2Cl] and [Cp4Ti4Se7O]
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