Pentacoordinate Organoaluminum Chemistry:  Catalytic Efficiency of Me3Al in the Epoxide Cleavage with Alkynyllithiums

Author:

Ooi Takashi1,Kagoshima Naoko1,Ichikawa Hayato1,Maruoka Keiji1

Affiliation:

1. Contribution from the Department of Chemistry, Graduate School of Science, Hokkaido University Sapporo 060-0810, Japan

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference15 articles.

1. Review:  (a) Klunder, J. M.; Posner, G. H. InComprehensive OrganicSynthesis; Trost, B. M., Fleming, I., Paquette, L. A., Eds.; Pergamon Press:  New York, 1991; Vol. 3, Chapter 1.5, p 207. (b) Knight, D. W. InComprehensive Organic Synthesis; Trost, B. M., Fleming, I., Paquette, L. A., Eds.; Pergamon Press:  New York, 1991; Vol. 3, Chapter 1.6, p 241. (c) Garratt, P. J. InComprehensive Organic Synthesis; Trost, B. M., Fleming, I., Paquette, L. A., Eds.; Pergamon Press:  New York, 1991; Vol. 3, Chapter 1.7, p 271. (d) Gorzynski, S. J.Synthesis1984, 629.

2. Mechanism and synthetic utility of boron trifluoride etherate-promoted organolithium additions

3. Fluorine-Assisted Selective Alkylation to Fluorinated Epoxides and Carbonyl Compounds:  Implication of Pentacoordinate Trialkylaluminum Complexes

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