Cyclizations of 3-Chlorocarbanions to Cyclopropanes: “Strain-Free” Transition States for Forming Highly Strained Rings
Author:
Affiliation:
1. Contribution from the Department of Chemistry and Biochemistry, San Francisco State University, San Francisco, California 94132
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja974068z
Reference36 articles.
1. Strain-Free Transition States in the Formation of Strained Rings: An ab Initio Study of Thiirane, Thietan, and Tetrahydrothiophene
2. A Correlation of Reaction Rates
3. Activation parameters for intramolecular nucleophilic substitution by carbanions—the insignificant effect of ring strain on cyclisation rates
4. Quantitative evaluation of steric effects in SN2 ring closure reactions
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