Trans → Cis Isomerization of trans-[(dppm)2Ru(H)(L)][BF4] (L = P(OR)3) Complexes: Preparation of cis-[(dppm)2Ru(η2-H2)(L)][BF4]2-Reference-Cited by-同舟云学术

Trans → Cis Isomerization of trans-[(dppm)2Ru(H)(L)][BF4] (L = P(OR)3) Complexes: Preparation of cis-[(dppm)2Ru(η2-H2)(L)][BF4]2

Published:2002-12-10 Issue:1 Volume:42 Page:187-197
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Mathew Nisha¹,Jagirdar Balaji R.¹,Ranganathan Anupama¹

Affiliation:

1. Department of Inorganic & Physical Chemistry, Indian Institute of Science, Bangalore 560 012, India, and Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore 560 064, India

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ic020082n

Reference59 articles.

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2. Influence of the Cone Angles and the π-Acceptor Properties of Phosphorus-Containing Ligands in the Chemistry of Dihydrogen Complexes of Ruthenium

3. Effect of the Ligand and Metal on the pKa Values of the Dihydrogen Ligand in the Series of Complexes [M(H2)H(L)2]+, M = Fe, Ru, Os, Containing Isosteric Ditertiaryphosphine Ligands, L

4. Influence of Chloride versus Hydride on H-H Bonding and Acidity of the Trans Dihydrogen Ligand in the Complexes trans-[Ru(H2)X(PR2CH2CH2PR2)2]+, X = Cl, H, R = Ph, Et. Crystal Structure Determinations of [RuCl(dppe)2]PF6 and trans-[Ru(H2)Cl(dppe)2]PF6

5. Synthesis of the acidic dihydrogen complexes trans-[M(H2)(CN)L2]+ and trans-[M(H2)(CNH)L2]2+ where M = Fe, Ru, Os and L = dppm, dppe, dppp, depe, and dihydrogen substitution by the trifluoromethanesulfonate anion to give trans-[Ru(OTf )(CN)L2] or trans-[Ru(OTf )(CNH)L2]OTf †

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