Preparation and Solution Properties of Chalcogenide-Rich Clusters [Mo3Y7(H2O)6]4+ (Y = S, Se): Kinetics of PR33- Abstraction of Y from μ-(Y22-) and H2O Substitution by Cl- and Br--Reference-Cited by-同舟云学术

Preparation and Solution Properties of Chalcogenide-Rich Clusters [Mo3Y7(H2O)6]4+ (Y = S, Se): Kinetics of PR33- Abstraction of Y from μ-(Y22-) and H2O Substitution by Cl- and Br-

Published:1997-07-01 Issue:14 Volume:36 Page:2982-2987
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Saysell David M.¹,Fedin Vladimir P.¹,Lamprecht Gert J.¹,Sokolov Maxim N.¹,Sykes A. Geoffrey¹

Affiliation:

1. Department of Chemistry, The University of Newcastle, Newcastle upon Tyne NE1 7RU, U.K.

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ic961343u

Reference32 articles.

1. Synthetic, spectroscopic, x-ray structural, and quantum-chemical studies of cyanothiomolybdates with Mo2S2, Mo3S4 and Mo4S4 cores: a remarkable class of species existing with different electron populations and having the same central units as the ferredoxins

2. Oxidative fragmentation of the cuboid molybdenum-sulfur Mo4S4 cluster core: synthesis and structures of [Mo3(.mu.3-S)(.mu.-S)3([9]aneN3)3]4+ and {[MoO([9]aneN3)]2(.mu.-S)2}2+ ([9]aneN3 = 1,4,7-triazacyclononane)

3. Preparation of trinuclear molybdenum(IV) ion, Mo3S4+4, and x-ray structure of Ca[Mo3S4 {HN(CH2CO2)2}3] · 11.5H2O

4. Reaction paths in the formation of triangular and cuboidal molybdenum/sulfur cluster complexes as aqua ions by reduction of molybdenum(V) dimers

5. Solution properties and reactivity of the aqua ion of the trimolybdenum(IV) incomplete cuboidal Mo/S cluster nonaaquatetrasulfidotrimolybdenum(4+)

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