Palladium Vacataporphyrin Reveals Conformational Rearrangements Involving Hückel and Möbius Macrocyclic Topologies

Author:

Pacholska-Dudziak Ewa1,Skonieczny Janusz1,Pawlicki Miłosz1,Szterenberg Ludmiła1,Ciunik Zbigniew1,Latos-Grażyński Lechosław1

Affiliation:

1. Department of Chemistry, University of Wrocław, Joliot-Curie 14, 50 383 Wrocław, Poland

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference128 articles.

1. A Direct Link between Annulene and Porphyrin Chemistry—21-Vacataporphyrin

2. From now on we will use the symbol (VPH2-n) to denote the hypothetical monoanion obtained from the vacataporphyrin by abstraction of a pyrrolic NH proton. The hypothetical dianion formed by abstraction the C-bound proton H(2) is noted as (VPH-n). The group attached to C(2/3) will appear as a suffix. Finally the appropriate macrocyclic conformers are systematically numbered (n) as occur in the text. The neutral structure is described by the following acronym (VPH2-n)H.

3. Novel Porphyrinoids for Chemistry and Medicine by Biomimetic Syntheses

4. Contracted and Expanded meso-Alkynyl Porphyrinoids:  from Triphyrin to Hexaphyrin

5. Tribenzosubporphines: Synthesis and Characterization

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