A Copper(I) Homocubane Collapses to a Tetracapped Tetrahedron Upon Hydride Insertion
Author:
Affiliation:
1. Department of Chemistry, National Dong Hwa University, Hualien, Taiwan 97401, R. O. C.
2. Department of Chemistry, Texas A&M University, College Station, TX 77842-3012, United States
3. Rezwave Techology Inc. His-Chih, Taiwan, R. O. C.
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic2009896
Reference33 articles.
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3. Metallocubanes. Crystal and molecular structures of tetrakis(tetraphenylphosphonium) hexakis(dithiosquarato)octacuprate(I) and tetrakis(tetrabutylammonium) hexakis(1,1-dicarboethoxyethylene-2,2-dithiolato) octacuprate(I) clusters with a common Cu8S12 core
4. Sulfur addition to the 1,1-dithiolate ligands in the [Cu8L6]4- cubanes (L = 1,1-dicarbo-tert-butoxy-2,2-ethylene dithiolate). Reversible Cu8(LS)64- to Cu4(LS)32- transformations
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