Structures of M2(SO2)6B12F12 (M = Ag or K) and Ag2(H2O)4B12F12: Comparison of the Coordination of SO2 versus H2O and of B12F122– versus Other Weakly Coordinating Anions to Metal Ions in the Solid State-Reference-Cited by-同舟云学术

Structures of M2(SO2)6B12F12 (M = Ag or K) and Ag2(H2O)4B12F12: Comparison of the Coordination of SO2 versus H2O and of B12F122– versus Other Weakly Coordinating Anions to Metal Ions in the Solid State

Published:2016-11-14 Issue:23 Volume:55 Page:12254-12262
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Malischewski Moritz¹,Peryshkov Dmitry V.²³,Bukovsky Eric V.²,Seppelt Konrad¹,Strauss Steven H.²

Affiliation:

1. Institut für Chemie und Biochemie, Freie Universität Berlin, 14195 Berlin, Germany

2. Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, United States

3. Department of Chemistry and Biochemistry, University of South Carolina, Columbia, South Carolina 29208, United States

Funder

Air Force Research Laboratory

Deutsche Forschungsgemeinschaft

Verband der Chemischen Industrie

Argonne National Laboratory

Colorado State University Foundation

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.6b01980

Reference51 articles.

1. Latent Porosity in Potassium Dodecafluoro-closo-dodecaborate(2−). Structures and Rapid Room Temperature Interconversions of Crystalline K2B12F12, K2(H2O)2B12F12, and K2(H2O)4B12F12 in the Presence of Water Vapor

2. K2B12F12: A rare A2X structure for an ionic compound at ambient conditions

3. Co-crystallization of octahedral and icosahedral fluoroanions in K3(AsF6)(B12F12) and Cs3(AsF6)(B12F12). Rare examples of salts containing fluoroanions with different shapes and charges

4. Pairing heterocyclic cations with closo-dodecafluorododecaborate (2−)

5. Solid-state solvation and anion packing patterns in X-ray structures of crystalline K2(solv)nB12F12 (solv=H2O2(aq), CH3OH, CH3NO2, and CH3CN)

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