Electrochemical Oxidation of [1-X-12-I-CB11Me10–] Anions: Formation of Borenium Ylides [12-Dehydro-1-X-CB11Me10] and Iodonium Ylide Anions [{12-(1-X-CB11Me10

Electrochemical Oxidation of [1-X-12-I-CB11Me10–] Anions: Formation of Borenium Ylides [12-Dehydro-1-X-CB11Me10] and Iodonium Ylide Anions [{12-(1-X-CB11Me10–)}2I+]

Published:2016-11-30 Issue:24 Volume:55 Page:12815-12821
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Wahab Abdul¹²^ORCID,Kaleta Jiří²,Wen Jin²³,Valášek Michal²,Polášek Miroslav¹,Michl Josef²³^ORCID,Ludvík Jiří¹

Affiliation:

1. J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejškova 3, 182 23 Prague 8, Czech Republic

2. Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, Flemingovo nám. 2, 166 10 Prague 6, Czech Republic

3. Department of Chemistry and Biochemistry, University of Colorado, Boulder, Colorado 80309-0215, United States

Funder

Division of Chemistry

Grantová Agentura Ceské Republiky

Ústav organické chemie a biochemie AV CR, v.v.i.

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.6b02128

Reference47 articles.

1. Chemistry of the Carba-closo-dodecaborate(−) Anion, CB11H12-

2. Update 1 of:Chemistry of the Carba-closo-dodecaborate(−) Anion, CB11H12–

3. HCB11(CF3)nF11-n−: Inert Anions with High Anodic Oxidation Potentials

4. The least coordinating anion

5. The search for larger and more weakly coordinating anions

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