Spin-Blocking Effect in CO and H2 Binding Reactions to Molybdenocene and Tungstenocene: A Theoretical Study on the Reaction Mechanism via the Minimum Energy Intersystem Crossing Point-Reference-Cited by-同舟云学术

Spin-Blocking Effect in CO and H2 Binding Reactions to Molybdenocene and Tungstenocene: A Theoretical Study on the Reaction Mechanism via the Minimum Energy Intersystem Crossing Point

Published:2016-08-02 Issue:16 Volume:55 Page:8082-8090
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Watanabe K-jiro¹²,Nakatani Naoki¹,Nakayama Akira¹,Higashi Masahiro²,Hasegawa Jun-ya¹

Affiliation:

1. Institute for Catalysis, Hokkaido University, N21 W10 Kita-ku, Sapporo, Hokkaido 001-0021, Japan

2. Department of Chemistry, Biology and Marine Science, Faculty of Science, University of the Ryukyus, 1 Senbaru, Nishihara, Okinawa 903-0213, Japan

Funder

Ministry of Education, Culture, Sports, Science, and Technology

Core Research for Evolutional Science and Technology, Japan Science and Technology Agency

Japan Society for the Promotion of Science

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.6b01187

Reference44 articles.

1. .alpha.-Elimination Can Be Faster than .beta.-Elimination in d2 Alkyl Complexes of Molybdenum and Tungsten That Contain the Trimethylsilyl-Substituted Triamidoamine Ligand

2. Modelling spin-forbidden reactions: recombination of carbon monoxide with iron tetracarbonyl

3. Do Spin State Changes Matter in Organometallic Chemistry? A Computational Study

4. Open-Shell Organometallics as a Bridge between Werner-Type and Low-Valent Organometallic Complexes. The Effect of the Spin State on the Stability, Reactivity, and Structure

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