Characterization of Rh–Al Bond in Rh(PAlP) (PAlP = Pincer-type Diphosphino-Aluminyl Ligand) in Comparison with Rh(L)(PMe3)2 (L = AlMe2, Al(NMe2)2, BR2, SiR3, CH3, Cl, or OCH3): Theoretical Insight
Author:
Affiliation:
1. Fukui Institute for Fundamental Chemistry, Kyoto University, Takano-Nishi-hiraki-cho, 34-4, Sakyo-ku, Kyoto 606-8103, Japan
2. Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 615-8510, Japan
Funder
Ministry of Education, Culture, Sports, Science and Technology
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.8b03493
Reference94 articles.
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2. Modularly Designed Transition Metal PNP and PCP Pincer Complexes based on Aminophosphines: Synthesis and Catalytic Applications
3. Reactions of Aromatic N-Heterocycles with d0fn-Metal Alkyl Complexes Supported by Chelating Diamide Ligands
4. Catalysis by Palladium Pincer Complexes
5. Metal–Ligand Cooperation by Aromatization–Dearomatization: A New Paradigm in Bond Activation and “Green” Catalysis
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