DFT Study on the Mechanism of Hydrogen Storage Based on the Formate-Bicarbonate Equilibrium Catalyzed by an Ir-NHC Complex: An Elusive Intramolecular C

DFT Study on the Mechanism of Hydrogen Storage Based on the Formate-Bicarbonate Equilibrium Catalyzed by an Ir-NHC Complex: An Elusive Intramolecular C–H Activation

Published:2018-04-27 Issue:10 Volume:57 Page:5903-5914
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Fehér Péter Pál¹²,Horváth Henrietta³,Joó Ferenc¹³^ORCID,Purgel Mihály¹^ORCID

Affiliation:

1. Department of Physical Chemistry, University of Debrecen, Egyetem tér 1, Debrecen H-4032, Hungary

2. Research Centre for Natural Sciences, Hungarian Academy of Sciences, Magyar tudósok körútja 2, H-1117 Budapest, Hungary

3. MTA-DE Redox and Homogeneous Catalytic Reaction Mechanisms Research Group, Debrecen, P.O. Box 400, H-4002, Hungary

Funder

European Commission

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.8b00382

Reference69 articles.

1. Formic acid as a hydrogen source – recent developments and future trends

2. Hydrogen energy future with formic acid: a renewable chemical hydrogen storage system

3. Reversible hydrogen storage using CO2 and a proton-switchable iridium catalyst in aqueous media under mild temperatures and pressures

4. CO2-“Neutral” Hydrogen Storage Based on Bicarbonates and Formates

5. Hydrogenation of CO2 at Room Temperature and Low Pressure with a Cobalt Tetraphosphine Catalyst

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