Ir(IV) Sulfoxide-Pincer Complexes by Three-Electron Oxidative Additions of Br2 and I2. Unprecedented Trap-Free Reductive Elimination of I2 from a formal d5 Metal-Reference-Cited by-同舟云学术

Ir(IV) Sulfoxide-Pincer Complexes by Three-Electron Oxidative Additions of Br₂ and I₂. Unprecedented Trap-Free Reductive Elimination of I₂ from a formal d⁵ Metal

Published:2022-01-06 Issue:3 Volume:61 Page:1236-1248
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Frieß Sibylle¹,Benyak Anna¹,Herrera Alberto¹,Escalona Ana M.¹,Heinemann Frank W.¹^ORCID,Langer Jens¹^ORCID,Fehn Dominik¹,Pividori Daniel¹,Grasruck Alexander¹,Munz Dominik¹²^ORCID,Meyer Karsten¹^ORCID,Dorta Romano¹^ORCID

Affiliation:

1. Department Chemie und Pharmazie, Anorganische Chemie, Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Egerlandstraße 1, 91058 Erlangen, Germany

2. Anorganische Chemie: Koordinationschemie, Universität des Saarlandes, Campus Geb. C4.1, 66123 Saarbrücken, Germany

Funder

Friedrich-Alexander-Universit??t Erlangen-N??rnberg

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.1c02956

Reference105 articles.

1. Cyclometalated Iridium(III) Aquo Complexes: Efficient and Tunable Catalysts for the Homogeneous Oxidation of Water

2. Highly Active and Robust Cp* Iridium Complexes for Catalytic Water Oxidation