Involvement of 5f Orbitals in the Covalent Bonding between the Uranyl Ion and Trialkyl Phosphine Oxide: Unraveled by Oxygen K-Edge X-ray Absorption Spectroscopy and Density Functional Theory-Reference-Cited by-同舟云学术

Involvement of 5f Orbitals in the Covalent Bonding between the Uranyl Ion and Trialkyl Phosphine Oxide: Unraveled by Oxygen K-Edge X-ray Absorption Spectroscopy and Density Functional Theory

Published:2021-11-24 Issue:1 Volume:61 Page:92-104
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Zhang Yusheng¹,Duan Wuhua¹,Yang Yuning¹,Jian Tian²^ORCID,Qiao Yusen²^ORCID,Ren Guoxi³,Zhang Nian³^ORCID,Zheng Lei⁴,Yan Wensheng⁵^ORCID,Wang Jianchen¹,Chen Jing¹,Minasian Stefan G.²^ORCID,Sun Taoxiang¹^ORCID

Affiliation:

1. Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China

2. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States

3. Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China

4. Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China

5. University of Science and Technology of China, National Synchrotron Radiation Laboratory, Hefei 230029, China

Funder

U.S. Department of Energy

National Natural Science Foundation of China

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.1c02236

Reference96 articles.

1. ACTINIDE PARTITIONING—A REVIEW

2. Recovery of Uranium from Wet Phosphoric Acid by Solvent Extraction Processes

3. Materials for the Recovery of Uranium from Seawater

4. Redox-switchable carboranes for uranium capture and release

5. Ligands for f-element extraction used in the nuclear fuel cycle

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