CNS and CNP Iron(II) Mono-Iron Hydrogenase (Hmd) Mimics: Role of Deprotonated Methylene(acyl) and the trans-Acyl Site in H2 Heterolysis
Author:
Affiliation:
1. Department of Chemistry, The University of Texas at Austin, Austin, Texas 78712, United States
Funder
Division of Chemistry
Welch Foundation
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.9b01530
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1. Hydrogenases
2. The Crystal Structure of [Fe]-Hydrogenase Reveals the Geometry of the Active Site
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4. The atomic-resolution crystal structure of activated [Fe]-hydrogenase
5. The crystal structure of C176A mutated [Fe]‐hydrogenase suggests an acyl‐iron ligation in the active site iron complex
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