Unraveling the Geometry-Driven C═C Epoxidation and C–H Hydroxylation Reactivity of Tetra-Coordinated Nonheme Iron(IV)

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Unraveling the Geometry-Driven C═C Epoxidation and C–H Hydroxylation Reactivity of Tetra-Coordinated Nonheme Iron(IV)–Oxo Complexes

Published:2024-07-19 Issue:31 Volume:63 Page:14468-14481
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Bhardwaj Akhil¹^ORCID,Mondal Bhaskar¹^ORCID

Affiliation:

1. School of Chemical Sciences, Indian Institute of Technology Mandi, Mandi, Himachal Pradesh 175075, India

Funder

Science and Engineering Research Board

Ministry of Education, India

Publisher

American Chemical Society (ACS)

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.4c01708

Reference75 articles.

1. Non-Heme Fe(IV)–Oxo Intermediates

2. High-Valent Iron(IV)–Oxo Complexes of Heme and Non-Heme Ligands in Oxygenation Reactions

3. High-valent nonheme iron-oxo complexes: Synthesis, structure, and spectroscopy

4. Tuning Reactivity and Mechanism in Oxidation Reactions by Mononuclear Nonheme Iron(IV)-Oxo Complexes

5. Synthetic Mononuclear Nonheme Iron–Oxygen Intermediates

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