Oxidation of Ni-ECp* Complexes: Stable Open-Shell NiI Cations [Ni(ECp*)n(PPh3)4–n]+ (n = 2, 4; E = Al, Ga)
Author:
Affiliation:
1. Anorganische Chemie II, Organometallics & Materials, Ruhr-Universität Bochum, D-44780 Bochum, Germany
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.5b01215
Reference39 articles.
1. N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands
2. Mixed phosphine and group-13 metal ligator complexes [(PR3)aM(ECp*)b] (M = Mo, Ni; E = Ga, Al; R = C6H5, cyclo-C6H11, CH3)
3. CH Activated Isomers of [M(AlCp*)5] (M=Fe, Ru)
4. AlCp* as a Directing Ligand: CH and SiH Bond Activation at the Reactive Intermediate[Ni(AlCp*)3]
5. The Clusters [Ma(ECp*)b] (M=Pd, Pt; E=Al, Ga, In): Structures, Fluxionality, and Ligand Exchange Reactions
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1. The chemistry of aluminum(I) with β-diketiminate ligands and pentamethylcyclopentadienyl-substituents: Synthesis, reactivity and applications;Coordination Chemistry Reviews;2018-11
2. Complexes of Ni(i): a “rare” oxidation state of growing importance;Chemical Society Reviews;2017
3. The Chemistry of Low-Valent Organoaluminum Species;PATAI'S Chemistry of Functional Groups;2016-12-19
4. [CpArNi{Ga(nacnac)}]: An Open-Shell Nickel(I) Complex Supported by a Gallium(I) Carbenoid (CpAr = C5(C6H4-4-Et)5, nacnac = HC[C(Me)N-(C6H3)-2,6-iPr2]2);Inorganic Chemistry;2016-03-07
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