Nanosized {Pd4(μ4-C)}Pd32(CO)28(PMe3)14 Containing Tetrahedrally Deformed Pd4 Cage with Encapsulated Carbide Atom: Formal Substitution of Geometrically Analogous Interior Au4 Entity in Isostructural Au4Pd32(CO)28(PMe3)14 by Electronically Equivalent Pd4(μ4-C) and Computational/Catalytic Implications-Reference-Cited by-同舟云学术

Nanosized {Pd4(μ4-C)}Pd32(CO)28(PMe3)14 Containing Tetrahedrally Deformed Pd4 Cage with Encapsulated Carbide Atom: Formal Substitution of Geometrically Analogous Interior Au4 Entity in Isostructural Au4Pd32(CO)28(PMe3)14 by Electronically Equivalent Pd4(μ4-C) and Computational/Catalytic Implications

Published:2015-05-06 Issue:13 Volume:54 Page:6157-6168
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Mednikov Evgueni G.¹,Ivanov Sergei A.²,Dahl Lawrence F.¹

Affiliation:

1. Department of Chemistry, University of Wisconsin-Madison, Madison, Wisconsin 53706, United States

2. Center for Integrated Nanotechnologies, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, United States

Funder

Hilldale Foundation, University of Wisconsin-Madison

University of Wisconsin-Madison

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.5b00208

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3. bJohnson, B. F. G.; Martin, C. M.InMetal Clusters in Chemistry;Braunstein, P.; Oro, L. A.; Raithby, P. R., Eds.Wiley-VCH:New York, 1999; Vol.2, pp877–912.

4. Chemistry of Ruthenium–Carbide Clusters Ru5C(CO)15 and Ru6C(CO)17

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