Potential Induced Protonation of the Second Coordination Sphere in a Hangman-type Iron Porphyrin Complex Promotes HER: Insights via in Situ Raman Spectroelectrochemistry

Author:

Ramuglia Anthony R.1,Göbel Markus1,Budhija Vishal2,Werheid Matthias1,Ly Khoa H.1,Schwalbe Matthias23ORCID,Weidinger Inez M.1ORCID

Affiliation:

1. Fakultät Chemie und Lebensmittelchemie, Technische Universität Dresden, Zellescher Weg 19, 01069 Dresden, Germany

2. Department of Chemistry, Humboldt-Universität zu Berlin, Brook-Taylor-Strasse 2, 12489 Berlin, Germany

3. Department of Chemistry, Utrecht University, Budapestlaan 4b, 3584 CD, Utrecht, Netherlands

Funder

Deutsche Forschungsgemeinschaft

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Reference59 articles.

1. Recent Advances in Electrocatalytic Hydrogen Evolution Using Nanoparticles

2. United States Department of Energy. A national vision of America’s transition to a hydrogen economy. To 2030 and beyond. Based on the results of the National Hydrogen Vision Meeting, Washington, DC, November 15–16, 2001. February 2002; p. 1–35.

3. Complexes of earth-abundant metals for catalytic electrochemical hydrogen generation under aqueous conditions

4. Earth-abundant hydrogen evolution electrocatalysts

5. Dissection of Electronic Substituent Effects in Multielectron–Multistep Molecular Catalysis. Electrochemical CO2-to-CO Conversion Catalyzed by Iron Porphyrins

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