Structural Diversities in Heterometallic Mn–Ca Cluster Chemistry from the Use of Salicylhydroxamic Acid: {MnIII4Ca2}, {MnII/III6Ca2}, {MnIII/IV8Ca}, and {MnIII8Ca2} Complexes with Relevance to Both High- and Low-Valent States of the Oxygen-Evolving Complex

Author:

Alaimo Alysha A.1,Koumousi Evangelia S.2,Cunha-Silva Luís3,McCormick Laura J.4ORCID,Teat Simon J.4,Psycharis Vassilis5,Raptopoulou Catherine P.5,Mukherjee Shreya6,Li Chaoran6,Gupta Sayak Das6,Escuer Albert7,Christou George6,Stamatatos Theocharis C.1ORCID

Affiliation:

1. Department of Chemistry, Brock University, 1812 Sir Isaac Brock Way, L2S 3A1 St. Catharines, Ontario, Canada

2. Department of Chemistry, University of Patras, 26504 Patras, Greece

3. REQUIMTE-LAQV & Department of Chemistry and Biochemistry, Faculty of Sciences, University of Porto, 4169-007 Porto, Portugal

4. Advanced Light Source, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, California 94720, United States

5. Institute of Nanoscience and Nanotechnology, NCSR “Demokritos”, 15310 Agia Paraskevi, Attikis, Greece

6. Department of Chemistry, University of Florida, Gainesville, Florida 32611-7200, United States

7. Departament de Quimica Inorganica and Institut de Nanociencia i Nanotecnologia (IN2UB), Universitat de Barcelona, Diagonal 645, 08028 Barcelona, Spain

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

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