Dehydration of the Uranyl Peroxide Studtite, [UO2(η2-O2)(H2O)2]·2H2O, Affords a Drastic Change in the Electronic Structure: A Combined X-ray Spectroscopic and Theoretical Analysis

Author:

Vitova Tonya1ORCID,Pidchenko Ivan1,Biswas Saptarshi2,Beridze George34,Dunne Peter W.2,Schild Dieter1,Wang Zheming5,Kowalski Piotr M.34,Baker Robert J.2ORCID

Affiliation:

1. Institute for Nuclear Waste Disposal (INE), Hermann-von-Helmholtz-Platz 1, D-76344 Eggenstein-Leopoldshafen, Germany

2. School of Chemistry, University of Dublin, Trinity College, College Green, Dublin 2, Ireland

3. Institute of Energy and Climate Research, IEK-6, Nuclear Waste Management and Reactor Safety, Forschungszentrum Jülich GmbH, Wilhelm-Johnen-Strasse, 52428 Jülich, Germany

4. JARA High-Performance Computing, Schinkelstrasse 2, 52062 Aachen, Germany

5. Pacific Northwest National Laboratory, MSIN K8-96, P.O. Box 999, Richland, Washington 99352, United States

Funder

Helmholtz-Gemeinschaft

Irish Research Council

Seventh Framework Programme

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

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