Linear MgCp*2 vs Bent CaCp*2: London Dispersion, Ligand-Induced Charge Localizations, and Pseudo-Pregostic C–H···Ca Interactions

Author:

Pal Rumpa1ORCID,Mebs Stefan2ORCID,Shi Ming W.3,Jayatilaka Dylan3,Krzeszczakowska Joanna M.4,Malaspina Lorraine A.1,Wiecko Michal5,Luger Peter5,Hesse Malte1,Chen Yu-Sheng6,Beckmann Jens1ORCID,Grabowsky Simon1ORCID

Affiliation:

1. Universität Bremen, Institut für Anorganische Chemie und Kristallographie, Leobener Straße 3 and 7, 28359 Bremen, Germany

2. Freie Universität Berlin, Institut für Experimentalphysik, Arnimallee 14, 14195 Berlin, Germany

3. The University of Western Australia, School of Molecular Sciences, 35 Stirling Highway, Perth Western Australia 6009, Australia

4. University of Warsaw, Biological and Chemical Research Centre, Chemistry Department, Zwirki i Wigury 101, 02-089 Warsaw, Poland

5. Freie Universität Berlin, Institut für Chemie und Biochemie, Anorganische Chemie, Fabeckstraße 36a, 14195 Berlin, Germany

6. ChemMatCARS, Center for Advanced Radiation Sources, c/o Advanced Photon Source/ANL, The University of Chicago, 9700 South Cass Avenue, Building 434D, Argonne, Illinois 60439, United States

Funder

Deutsche Forschungsgemeinschaft

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

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