Perovskite-Type InCoO3 with Low-Spin Co3+: Effect of In–O Covalency on Structural Stabilization in Comparison with Rare-Earth Series

Author:

Fujita Koji1ORCID,Kawamoto Takahiro1,Yamada Ikuya2ORCID,Hernandez Olivier3,Akamatsu Hirofumi4,Kumagai Yu5,Oba Fumiyasu45,Manuel Pascal6,Fujikawa Ryo1,Yoshida Suguru1,Fukuda Masayuki1,Tanaka Katsuhisa1

Affiliation:

1. Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan

2. Nanoscience and Nanotechnology Research Center, Osaka Prefecture University, 1-2 Gakuen-cho, Sakai, Osaka 599-8531, Japan

3. Institut des Sciences Chimiques de Rennes, Equipe Chimie du Solide et Matériaux, UMR CNRS 6226, Université de Rennes 1, 263 Avenue du Général Leclerc, 35042 Rennes, France

4. Laboratory for Materials and Structures, Institute of Innovative Research, Tokyo Institute of Technology, Yokohama 226-8503, Japan

5. Materials Research Center for Element Strategy, Tokyo Institute of Technology, Yokohama 226-8503, Japan

6. ISIS Facility, STFC Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Oxon OX11 0QX, United Kingdom

Funder

Japan Society for the Promotion of Science

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

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