Assessing the 4f Orbital Participation in the Ln–C Bonds of [Li(THF)<sub>4</sub>][Ln(C<sub>6</sub>Cl<sub>5</sub>)<sub>4</sub>] (Ln = La, Ce)-Reference-Cited by-同舟云学术

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Assessing the 4f Orbital Participation in the Ln–C Bonds of [Li(THF)₄][Ln(C₆Cl₅)₄] (Ln = La, Ce)

Published:2022-09-14 Issue:38 Volume:61 Page:15138-15143
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Ordoñez Osvaldo¹,Yu Xiaojuan²^ORCID,Wu Guang¹,Autschbach Jochen²^ORCID,Hayton Trevor W.¹^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, University of California Santa Barbara, Santa Barbara, California 93106, United States

2. Department of Chemistry, University at Buffalo, State University of New York, Buffalo, New York 14260, United States

Funder

Basic Energy Sciences

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.2c02304

Reference50 articles.

1. Dramatic enhancement of the stability of rare-earth metal complexes with α-methyl substituted N,N-dimethylbenzylamine ligands

2. Preparation and molecular structure of a σ-bonded lanthanide phenyl

3. Re-investigation of ortho-metalated N,N-dialkylbenzylamine complexes of rare-earth metals. First structurally characterized arylates of neodymium and gadolinium Li[LnAr4]

4. Homoleptic Rare-Earth Metal Complexes Containing Ln−C σ-Bonds

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