Mechanism of Catalytic Aziridination with Manganese Corrole: The Often Postulated High-Valent Mn(V) Imido Is Not the Group Transfer Reagent
Author:
Affiliation:
1. Contribution from the Brown Laboratory, Department of Chemistry, Purdue University, 560 Oval Drive,West Lafayette, Indiana 47907
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja0665489
Reference61 articles.
1. Enantioselective Catalytic Aziridinations and Asymmetric Nitrene Insertions into CH Bonds
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3. Activation and transfer of nitrogen from a nitridomanganese(V) porphyrin complex. Aza analog of epoxidation
4. Nitridomanganese(V) Complexes: Design, Preparation, and Use as Nitrogen Atom-Transfer Reagents
5. Metal complexes with tetrapyrrole ligands. 30. The manganese-nitrogen triple bond. Synthesis and molecular stereochemistry of (5,15-dimethyl-2,3,7,8,12,13,17,18-octaethyl-5H,15H-porphinato)nitridomanganese(V)
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