Electrochemistry of [Mo2Cp2(CO)4{μ-η2:η3-HC⋮C−C(R1)(R2)}]+ Complexes (R1 = H, R2 = H, Me, Et, Fc; R1 = Me, R2 = Me, Ph). Control of the Reduction Process (Two-Electron vs One-Electron) by the Substituents R1 and R2: EHMO Rationalization-Reference-Cited by-同舟云学术

Electrochemistry of [Mo2Cp2(CO)4{μ-η2:η3-HC⋮C−C(R1)(R2)}]+ Complexes (R1 = H, R2 = H, Me, Et, Fc; R1 = Me, R2 = Me, Ph). Control of the Reduction Process (Two-Electron vs One-Electron) by the Substituents R1 and R2: EHMO Rationalization

Published:1997-10-01 Issue:21 Volume:16 Page:4645-4656
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Capon Jean-François¹,Kergoat René¹,Le Berre-Cosquer Nathalie¹,Péron Stéphane¹,Saillard Jean-Yves¹,Talarmin Jean¹

Affiliation:

1. UMR 6521, Chimie, Electrochimie Moléculaires et Chimie Analytique, Département de Chimie, Université de Bretagne Occidentale, 6 Av V. Le Gorgeu, BP 809, 29285 Brest Cedex, France, Département de Mathématiques, Université de Bretagne Occidentale, 6 Av V. Le Gorgeu, BP 809, 29285 Brest Cedex, France, and UMR 6511, Chimie du Solide et Inorganique Moléculaire, Université de Rennes 1, Campus de Beaulieu, 35042 Rennes Cedex, France

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om970341u

Reference36 articles.

1. New Bonding Modes, Fluxional Behavior, and Reactivity in Dinuclear Complexes Bridged by Four-Electron Donor Unsaturated Hydrocarbons

2. Reaction of sodium amalgam with carbenium ions species stabilised by two adjacent organometallic moieties

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1. One-Electron and Two-Electron Transfers in Electrochemistry and Homogeneous Solution Reactions;Chemical Reviews;2008-07-01

2. Molybdenum Compounds with CO or Isocyanides;Comprehensive Organometallic Chemistry III;2007

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4. Oxidatively-induced μ-η1→ μ-η1:η1rearrangement of {NN} ligands at a {Mo2(μ-SMe)3} site and protonation of the oxidized diazenido complex;New J. Chem.;2006

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