In Search of the Bailar and Rây−Dutt Twist Mechanisms That Racemize Chiral Trischelates: A Computational Study of ScIII, TiIV, CoIII, ZnII, GaIII, and GeIV Complexes of a Ligand Analogue of Acetylacetonate-Reference-Cited by-同舟云学术

In Search of the Bailar and Rây−Dutt Twist Mechanisms That Racemize Chiral Trischelates: A Computational Study of ScIII, TiIV, CoIII, ZnII, GaIII, and GeIV Complexes of a Ligand Analogue of Acetylacetonate

Published:2007-08-24 Issue:19 Volume:46 Page:8024-8031
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Rzepa Henry S.¹,Cass Marion E.¹

Affiliation:

1. Department of Chemistry, Imperial College London, London SW7 2AZ, U.K., and Department of Chemistry, Carleton College, Northfield, Minnesota 55057

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ic062473y

Reference35 articles.

1. Some problems in the stereochemistry of coordination compounds

2. Intramolecular isomerization of octahedral complexes by nonbond-rupture mechanisms

3. Mechanistic study of titanate-catalyzed transesterification: influence of aggregation on reactivity

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