Insertion of Ethyne into the Ru−Si Bonds of Coordinatively Unsaturated Ruthenium Silyl Complexes. X-ray Crystal Structures of Ru(CHCHSiMe2OEt)Cl(CO)2(PPh3)2 and [Ru(CHCHSiMe2OH)(CN-p-tolyl)(CO)(PPh3)2]ClO4-Reference-Cited by-同舟云学术

Insertion of Ethyne into the Ru−Si Bonds of Coordinatively Unsaturated Ruthenium Silyl Complexes. X-ray Crystal Structures of Ru(CHCHSiMe2OEt)Cl(CO)2(PPh3)2 and [Ru(CHCHSiMe2OH)(CN-p-tolyl)(CO)(PPh3)2]ClO4

Published:1996-04-02 Issue:7 Volume:15 Page:1793-1803
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Maddock Susan M.¹,Rickard Clifton E. F.¹,Roper Warren R.¹,Wright L. James¹

Affiliation:

1. Department of Chemistry, University of Auckland, Private Bag 92019, Auckland, New Zealand

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om9509711

Reference23 articles.

1. Reactivity of the metal-silicon bond in organometallic chemistry

2. Dehydrogenative silation, isomerization and the control of syn- vs. anti-addition in the hydrosilation of alkynes

3. Hydrosilylation of 1-hexyne catalyzed by rhodium and cobalt-rhodium mixed-metal complexes. Mechanism of apparent trans addition

4. Insertion of acetylenes into the silicon-platinum bond, affording (.beta.-silylvinyl)platinum complexes

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